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Journal of high energy chemistry archive numbers. What he studies: High energy chemistry

Scientometric indicators

Usage
  • 6795 Full Text Downloads 2018

    Springer measures the number of downloads of full texts from the SpringerLink platform in accordance with COUNTER (Counting Online Usage of NeTworked Electronic Resources) standards.

  • 23 Usage factor 2017/2018

    The usage factor is a value calculated according to the rules recommended by COUNTER. This is the average (median) number of downloads in 2017/18. for all articles published online in the same journal during the same period. The usage factor calculation is based on data that complies with the COUNTER standards on the SpringerLink platform.

Influence
  • 0.634 Impact Factor 2018

    Impact factor published by Clarivate Analytics in Journal Citation Reports. Impact factors refer to the previous year.

  • 0.59 Source Normalized Impact per Paper (SNIP) 2018

    Source Normalized Impact per Paper (SNIP) measures a journal's contextual citation impact by weighting the citations in each subject group. The contribution of each individual citation is the higher in each specific subject category, the less likely (for reasons of subject content) that such a citation will occur.

  • Q4 Quartile: Physical and Theoretical Chemistry 2018

    A set of journals from the same subject category are ranked according to their SJR and divided into 4 groups called quartiles. Q1 (green) combines the journals with the highest scores, Q2 (yellow) - following them, Q3 (orange orange) - the third group in terms of SJR, Q4 (red) - journals with the lowest scores.

  • 0.27 SCImago Journal Rank (SJR) 2018

    SCImago Journal Rank (SJR) is a measure of a journal's scientific impact that takes into account the number of citations a journal receives and the rating of citing journals.

  • 19 h-index 2018

SCOPE

High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.

Indexing and referencing

Chemical Abstracts Service (CAS), Chimica, Current Contents/Physical, Chemical and Earth Sciences, EBSCO Academic Search, EBSCO Advanced Placement Source, EBSCO Discovery Service, EBSCO Engineering Source, EBSCO Environment, EBSCO STM Source, Gale, Gale Academic OneFile, Gale InfoTrac, Google Scholar, INIS Atomindex, INSPEC, Institute of Scientific and Technical Information of China, Japanese Science and Technology Agency (JST), Journal Citation Reports/Science Edition, Naver, OCLC WorldCat Discovery Service, ProQuest Central, ProQuest Materials Science and Engineering Database, ProQuest SciTech Premium Collection, ProQuest Technology Collection, ProQuest-ExLibris Primo, ProQuest-ExLibris Summon, Reaction Citation Index, Reaxys, SCImago, SCOPUS, Science Citation Index, Science Citation Index Expanded (SciSearch), Semantic Scholar.

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2.2. Works (Content) - electronic versions of scientific publications, including periodicals, as well as non-periodical publications, presented in electronic form on the Internet in various formats, posted on the "Electronic Library System" Website, available to Users through the "Electronic Library System" Website.

2.3. Catalog - a collection of Works.

2.4. Login and Password are two unique character sets that identify the User.

2.5. The site "Electronic Library System" is an information resource on the Internet, owned by the Federal State Unitary Enterprise "Publishing House" Nauka ", located on the domain www. .

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3. Subject of the Agreement

3.1. "Electronic Library System" provides the User with the opportunity to view, read and download the Works presented in the Catalog on a paid basis.

3.2. The User can issue and pay for a preliminary annual (partial annual) subscription to the ability to view, read and download electronic versions of the Works, as well as a preliminary subscription to the ability to receive a collection of Works that are not placed in the Catalog at the time of registration and payment.

4. Obligations of the parties

4.1. Responsibilities of the Site Administrator:

4.1.1. Provide the User with the opportunity to view, read and download the Work on the Site no later than 24 hours from the moment the Billing confirms the payment made and identifies the User as the payer of the payment made. In the case of registration and payment by the User of a preliminary subscription in accordance with clause 3.2. of the Agreement, to provide the User with the opportunity to view, read and download the Works no later than 24 hours from the moment they are placed in the Catalog, subject to confirmation by the Billing of the earlier payment and identification of the User as the payer of the payment made.

4.1.2. Do not disclose to third parties the Login and Password, the User's e-mail address, as well as other information received from the User during registration.

4.1.3. Notify the User about changes in the terms of the Agreement and its Applications by posting relevant information on the Website of the "Electronic Library System" at least 30 (thirty) calendar days before the changes take effect.

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4.2.1. Register on the website of the Electronic Library System. Set Login and Password, the uniqueness of which is confirmed by the "Site Administration". At the same time, strictly and strictly follow the instructions of the Site Administration on the registration procedure posted on the Site of the "Electronic Library System".

4.2.2. Pay for the opportunity to view, read and download the Works in accordance with clause 4 of the Agreement.

4.2.3. Ensure the confidentiality of the Login and Password provided during registration.

4.2.4. Use the downloaded Works solely for personal purposes. In this case, the User is granted the following rights to use the Works:

  • carry out remote access on the Internet through the Site of the "Electronic Library System" to the Works, which means the ability to search, view, download and read the Works.
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  • transfer or distribute the downloaded Works to third parties, either in full or in part, except as provided in clause 4.2.4. Agreements;
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4.2.6. All information posted on the Website of the "Electronic Library System" about the procedure for using the Catalog, the procedure for payment and other features of the execution of the Agreement is an integral part of the Agreement and is binding on the User.

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5.1. The User makes an advance payment in Russian rubles on the terms specified on the Electronic Library System Website.

5.2. Payment methods are indicated on the Site in the Payment Methods section. The agreed payment method is the method chosen by the User from the available payment methods on the Electronic Library System Website.

5.3. The procedure for paying with bank cards is indicated on the Site in the Payment Methods section. Transactions using bank cards can be made exclusively by the cardholder. Bank card transactions are authorized by the bank. Acceptance and processing of payments using bank cards is carried out by the Yandex.Checkout electronic payment provider or another electronic payment provider. The "Site Administration" does not process, including the collection and storage of Users' bank card data.

5.4. The price of enabling the User - an individual to view, read and download the Works is indicated on the Website of the "Electronic Library System" in the relevant sections. For users who are legal entities, prices are sent by the "Site Administration" upon request through agreed communication channels. The “Site Administration” has the right to unilaterally change the current prices by posting relevant information on the “Electronic Library System” Website or informing Users in another accessible way. Any change in prices does not apply to already paid access.

6. Responsibility of the parties. Limitation of Liability of "Electronic Library System".

6.1. The User assumes full responsibility and risks associated with the use of the Catalog.

6.2. The User is fully responsible for the use by third parties of the Login and Password.

6.3. The User is fully responsible for the use by third parties of the information transmitted by the "Site Administration" to the e-mail address specified by the User during registration.

6.4. The "Site Administration" is not responsible for any expenses of the User or direct or indirect damage that may be caused to the User as a result of using the Catalog.

6.5. "Site Administration" is not responsible for the quality of access to the Catalog via the Internet.

6.6. Under no circumstances is the "Site Administration" responsible for the use of the Login and Password by third parties.

6.7. The “Site Administration” is not responsible for direct or indirect damage incurred by the User as a result of data transmission errors, failures / defects in the operation of software and / or equipment, data loss and damage, data processing or display errors, delays in data transmission and others. failures that occurred through no fault of the "Site Administration".

6.8. The Electronic Library System website and all related services are provided on an "as is" basis, without any express or implied warranties that the specified Website and (or) services may or may not be suitable for specific purposes of use.

6.9. The "Site Administration" is not responsible for the impossibility of using the Site, and (or) related services by the User for any reason, including, but not limited to: errors, omissions, interruptions, deletion, defects, delay in processing or transmission of data, disruption of work communication lines, equipment malfunction, any technical failures or other problems of any telephone networks or services, computer systems, servers or providers, computer or telephone equipment, software, failure to fulfill obligations of providers of certain services, theft, destruction or unauthorized access to User materials posted on the Site or in any other place, etc.

6.10. Under no circumstances shall the "Site Administration" be liable for any expenses of the User or direct or indirect damage, including lost profits or lost data, damage to honor, dignity or business reputation that may be caused to the User as a result of using the Site and (or) related services .

6.11. If it is impossible for the "Electronic Library System" to provide the User with the opportunity to view, read and download the Work for reasons beyond the control of the "Site Administration", the "Site Administration" at the request of the User returns the received advance payment. At the same time, the amount of responsibility of the "Site Administration" is limited to the amount of the advance payment received from the User for the opportunity to view, read and download the Work, which was not provided.

7. Duration of the Agreement

7.1. The Agreement comes into force from the moment the User accepts the terms of the Agreement (each Appendix to the Agreement comes into force from the moment the User accepts the terms of this Appendix) and is valid until the Parties fully fulfill their obligations.

8. Force majeure circumstances

8.1. The Parties are released from liability for partial or complete failure to fulfill obligations under this Agreement if such failure was a direct result of force majeure circumstances (force majeure) that arose after the conclusion of the Agreement, as a result of extraordinary events, namely: fire, flood, hurricane and earthquake or the imposition of restrictions by state authorities on the activities of any of the Parties, and if these circumstances the Parties could neither foresee nor prevent reasonable measures.

9. Other terms

9.1. In the event that any provision or any part of the Agreement is held invalid or unenforceable, the remaining provisions and parts of the Agreement shall remain in full force and effect.

9.2. In all other respects, the Parties to the Agreement agreed to be guided by the current legislation of the Russian Federation.

9.3. The “Site Administration” has the right to make changes to the Agreement with the obligatory posting of the relevant information on the “Electronic Library System” Website no later than 30 (thirty) calendar days before the relevant changes come into force.

9.4. Relations between the "Site Administration" and the User, which are legal entities, are regulated on the basis of separately concluded Agreements, which specify the specific conditions for the relationship between the Parties.

9.5. For any questions that arise, the User has the right to contact the Site Support Service at the email address:

10. Dispute Resolution

10.1. Disputes and disagreements that may arise under this Agreement are resolved by observing the pre-trial (claim) procedure. The term for consideration by the "Site Administration" of the claim is 10 (ten) calendar days from the date of its receipt from the User.

10.2. If the Parties do not come to an agreement, these disputes and disagreements are resolved in court in accordance with the current legislation of the Russian Federation in the court at the location of FSUE Nauka Publishing House in accordance with the rules of jurisdiction and cognizance.

11. Privacy Notice

11.1. The User's consent to the provision of personal information is determined by agreement with this public offer, which occurs automatically when the User completes the registration procedure on the Site.

11.2. In accordance with the Federal Law "On Personal Data" No. 152-FZ of July 27, 2006 and this privacy policy, the Site Administration does not use, process or store the User's personal data.

11.3. The "Site Administration" collects and stores only the User's data necessary for the operation of the Site. The "Site Administration" may use the User's data to identify him, clarify payment data, provide personalized services, provide feedback to the User, process applications and requests, perform anonymous statistical calculations and improve the quality of services provided to the User.

The journal publishes original and review articles, short communications, letters to the editor on molecular and supramolecular photochemistry, radiation chemistry, plasma chemistry, chemistry of new atoms, processes and materials for optical information systems, on the scientific foundations of relevant technologies, as well as chronicles and reviews of books in the field high energy chemistry.

Starting from the second half of 2007, the journal will publish materials on scientific and applied photography. Previously (until 2003) the "Journal of Scientific and Applied Photography" was published as an independent publication.

Archive of scientific articles from the journal "High Energy Chemistry"

  • J-AGGREGATION OF THIACARBOCYANINE DYE IN REVERSE MICROEMULSIONS

    S. B. Brichkin, A. V. Ivanchikhina, A. V. Nevidimov, L. M. Nikolenko, V. F. Razumov, and S. A. Tovstun - 2015

    J-aggregation of thiacarbocyanine dye pyridinium salt 3,3-di-(-sulfopropyl)-4,5,4,5-dibenzo-9-ethylthiacarbocyanine betaine (DEC) in reverse microemulsions of sodium bis-(2-ethylhexyl) sulfosuccinate (AOT) was studied. )/n-hexane/water and polyoxyethylene (5) nonylphenyl ether (NP5)/cyclohexane/water. In such systems, the dye is present mainly as a trans monomer and a J-aggregate. It is shown that the equilibrium between these forms is determined by the solubility of the trans monomer in monolayers of surfactant molecules covering microemulsion drops. When the total concentration of the dye in the microemulsion is less than the solubility, the equilibrium state corresponds to the presence of the dye only in the form of a trans monomer. When the concentration exceeds the solubility, the excess dye forms J-aggregates, which gradually coarsen and precipitate. For inverse AOT/n-hexane/water microemulsions, the found solubility was / = (1.45 ± 0.34) × 10-5.

  • LASER PLASMA INTERACTION DURING VISIBLE AND IR LASER ABLATION OF CHROMITE MINERAL TARGET

    HANIF M., SALIK M., WANG J., ZHANG X.Q. - 2015

    In this work, we present optical emission studies of the laser induced Chromite mineral plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched pulsed Nd: YAG laser. The spectra predominantly reveal the spectral lines of neutral Cr as well as dominant spectral lines of constituent elements. The experimentally observed line profiles of neutral chromium have been used to extract the electron temperature (Te) using the Boltzmann plot method. Whereas, the electron number density (Ne) has been determined from the Stark broadened line profiles. We have also studied the variation of electron temperature and electron number density as a function of laser irradiance at atmospheric pressure. We have also studied the variation of these plasma parameters (Te and Ne) as a function of the laser irradiance as well as distance along the direction of plasma plume. The validity of the assumption of local thermodynamic equilibrium (LTE) is also discussed in the light of the experimental data and analysis.

  • PREPARATION OF COLLOIDAL LEAD SULFIDE NANOPARTICLES BY LASER ABLATION IN WATER FOR OPTOELECTRONIC DEVICES APPLICATIONS

    ISMAIL RAID A. - 2015

    In present work, lead sulfide PbS nanoparticles NPs are synthesized by laser ablation of lead sulfide target in double distilled water using 0.532 and 1.064 wavelengths. The transmission electron microscopy TEM, atomic force microscopy AFM and X-ray diffraction XRD were used so as to determine the shape, size, distribution, and structure of the nanoparticles prepared with different laser wavelengths. X-ray diffraction results confirmed that the lead sulfide nanoparticles crystallized in the cubic phase and presents a preferential orientation along (200) plane and with no observation of any incomplete phases. Optical band gap values ​​of 1.9 and 2eV for the lead sulfide nanoparticles were determined by UV-Vis absorption measurements. It was found that the morphology and size of PbS NPs depend on laser wavelength. To check the possibility of synthesized nanoparticles for optoelectronic devices, a novel type of solution-processed heterojunction photodetector, prepared by drop cast film of colloidal lead sulfide nanoparticles NPs onto n-type single crystal silicon wafer was demonstrated. The effect of laser wavelength on the electrical characteristics and photosensitivity of p-PbS/n-Si heterojunction has been investigated.

  • THERMOLUMINESCENCE RESPONSE OF MULTIMODE FLUORINE-DOPED SIO2 OPTICAL FIBERS AND TLD 100 WITH 6 MEGA VOLT PHOTON IRRADIATION

    HOSSAIN I., MUBARAK A.A., NURSYAZWANIE R., SAEED M.A., WAGIRAN H. - 2015

    This study investigates and compares the results of thermoluminescence responses, its linearity, sensitivity with various dose ranges and TL glow curve of Fluorine-doped silica fiber and TLD-100 materials. The TL responses of the Fl-doped silica fibers and TLD 100 were kept in gelatin capsule and irradiated with 6-MV photon at the dose range from 0.5 Gy to 4.0 Gy. Siemens model Primus 3368 linear accelerator located at Hospital Sultan Ismail; Johor Bahru has been used to deliver the photon beam to the samples. The TL-signal of TLD 100 media exhibits a significant linear dose to signal relationship with an increase in doses. The sensitivity of Fl-doped optical fiber is negligible to TLD 100 media.

  • THERMOLUMINESCENCE RESPONSE OF YTTERBIUM-DOPED SILICON DIOXIDE FIBER

    ABDUL PATTAH N.F., HOSSAIN I., SAEED M.A., WAGIRAN H. - 2015

    In this study, thermoluminescence properties of Yb-doped of SiO2 optical fibers such as linearity, sensitivity and dose response have been studied. Samples were placed in the gelatin capsules to irradiate with photons from Cobalt-60 of the dose range between 10–100 Gy. The beams were provided by Gammacell 220, available at Universiti Kebangsaan Malaysia, Bangi, Malaysia. The glow curves were analyzed to determine various characteristics of the thermoluminescence. The TL response as a function of dose is linear up to 40 Gy. The sensitivity of Yb-doped optical fiber is 0.136 nC mg-1 Gy-1.

  • TIME FUNCTION TRIPLE LANGMUIR PROBE MEASUREMENTS IN LOW FREQUENCY PULSED DC DISCHARGE PLASMA

    ALI A., FAROOQ M.U., GHAFFAR CH. A., KHAN Y., NAZ M.Y., QAYYUM A., SHUKRULAH S. - 2015

    This study investigate the temporal profiles of electron temperature and number density in rectified DC air discharge generated with a 50 Hz step-up transformer. An in-house built triple Langmuir probe and circuitry were used to diagnose the plasma parameters as a function of input voltage and filling gas pressure. A tungsten metal wire capable of withstanding the high temperatures was used as probe tip material. The temporal profiles revealed an increase in electron temperature with input voltage in the range of 380 to 450 V, whereas, an inverse relation between number density and input voltage was evident in the given work. The observed trend in the plasma parameters was absolutely reversed in case of the filling gas pressure. The electron temperature linearly decreased with an increase in pressure from 1 to 4 mbar, whereas a linear increase in number density with pressure was seen in the temporal profiles. Finally, it was concluded that the results for the tested plasma parameters were consistent and the in-house built probe functioned well in DC discharge for the used range of voltage and filling pressure.

  • Interaction of Tryptophan and Its Derivatives with Oxygen- and Nitrogen-Centered Radicals

    S. D. Brinkevich, R. L. Sverdlov, A. V. Khrishchanovich, and O. I. Shadyro - 2015

    The interaction of tryptophan and its derivatives with nitrogen-centered 2,2-diphenyl-1-picrylhydrazyl radicals and oxygen-centered radicals formed during the radiolysis of oxygen-saturated ethanol and its aqueous solutions was studied. It has been established that tryptophan, 5-hydroxytryptophan, serotonin, harmane, harmine and harmaline, in contrast to pyrrole, indole and melatonin, are able to reduce oxygen-centered radicals due to the electron transfer reaction from the lone pair of nitrogen atoms. It was shown that serotonin and 5-hydroxytryptophan reduce 2,2-diphenyl-1-picrylhydrazyl radicals due to the reaction of hydrogen atom transfer from the hydroxyl groups of the molecules. At the same time, pyrrole, indole, tryptophan, melatonin, harmane, harmine, and harmaline, which do not contain a phenol-type hydroxyl group in their structure, do not interact with 2,2-diphenyl-1-picrylhydrazyl radicals. The end molecular products of the interaction of serotonin and 5-hydroxytryptophan with 2,2-diphenyl-1-picrylhydrazyl radicals were identified by chromatography-mass spectrometry.

  • RELATIONSHIP OF ADHESION, CONTACT, AND ELECTRET PROPERTIES OF POLYTETRAFLUOROETHYLENE FILMS MODIFIED IN A DC DISCHARGE

    A. B. Gilman, A. S. Kechek’yan, A. A. Kuznetsov, M. S. Piskarev, and M. Yu. Yablokov - 2015

    The relationship between the values ​​of the contact angle, peel resistance, and effective surface charge density of polytetrafluoroethylene films modified in a direct current discharge at the anode and cathode has been studied. It is shown that there is a correlation between the adhesive characteristics of the film treated in a DC discharge, the change in the wetting angle, and the value of the effective surface charge.

  • Vibronic Structure of the Electron Absorption and Fluorescence Spectra of Pyrene in a Complex with Beta-cyclodextrin in the Presence of Nonpolar and Polar Solvents

    V. G. Avakyan, M. V. Alfimov, A. V. Koshkin, and V. B. Nazarov - 2015

    The possibility of using pyrene (Py) as a fluorescent probe (FP) in cyclodextrin–pyrene–analyte complexes for analytes (A) of different polarity in aqueous solutions was studied. In the UV-VIS spectrum of an aqueous solution of Py in the presence of CD, bands were found for the first time, proving the formation of a complex [email protected] CD. The characteristic of the FC is the ratio I3/I1 in the fluorescence spectrum, where I3 is the intensity of the third vibronic line 800 cm-1, I1 is the intensity of the 0-0 transition. I3/I1 value for [email protected] CD is highly sensitive to the addition of A at a concentration of several M/L to an aqueous solution. Dependences (I3/I1)/C on the function of the dielectric constant А f = (– 1)/2 + 1) are divided into two straight lines with different slopes for non-polar and polar A. Interstitial energies A in [email protected] CDs were calculated using the PM3 quantum chemical method. An increase in (I3/I1)/C corresponds to a thermodynamically more stable complex 2А [email protected] CD.

  • EFFECT OF ALBUMIN AND WATER-SOLUBLE ANALOGUES OF VITAMINS E, Q, K ON FREE RADICAL FRAGMENTATION OF PHOSPHOLIPIDS

    MELSITOVA I.V., YURKOVA I.L. - 2015

    The effect of trolox C, ubiquinone Q0, phthicol, and bovine serum albumin (BSA) on the free radical fragmentation of dimyristoylphosphatidylglycerol (DMPG) in model membranes exposed to γ-irradiation was studied. It has been established that ubiquinone Q0 and phthicol are more effective (1.8–1.9 times) than Trolox C (1.5 times) in reducing the radiation-chemical yield of dimyristoylphosphatidic acid (DMPA), the molecular product of DMPG fragmentation. BSA has a protective effect on DMPG fragmentation in a dose-dependent manner; at a lipid:protein ratio (30:1), the DMPA yield is reduced by 2 times.

  • INFLUENCE OF ASCORBIC ACID AND ITS DERIVATIVES ON RADIATION-INDUCED CONVERSIONS OF OXYGENATED ETHANOL AND ITS AQUEOUS SOLUTIONS

    Brinkevich S.D. - 2015

    Under -irradiation of ethanol and its aqueous solutions at pH 7, saturated with oxygen, ascorbic acid is able to reduce the yields due to the reduction of peroxyl radicals, and 5,6-O-isopropylidyl-2,3-O-dimethylascorbic acid - due to the oxidation of -hydroxyethyl radicals the main products of radiolysis. In addition to the ability to inhibit radiation-induced transformations of oxygenated ethanol and its aqueous solutions at pH 7, ascorbic acid can enter into reactions leading to the formation of an additional amount of reactive oxygen species, which must be taken into account when considering its role in free radical processes in biosystems.

  • INFLUENCE OF HYPOCHLORITE ON THE RADIOLYSIS OF AQUEOUS PROPANOL-2

    KOSOBUTSKY V.S. - 2015

    DOI: 10.1134/S0023119315040105 References

  • INFLUENCE OF Illumination Intensity on the Rate and Selectivity of Photosensitized Oxidation of Dibutyl Sulfide on Fullerene C70

    A. V. Arsentiev, A. V. Vorontsov, and V. N. Parmon - 2015

    Photoinitiated oxidation of dibutyl sulfide (DBS) with atmospheric oxygen in a toluene solution of C70 fullerene under visible light at a wavelength of 500–700 nm leads to the formation of dibutyl sulfone as the main detected product, as well as dibutyl sulfoxide, dibutyl disulfide, and butanal. Changing the irradiance of the reaction mixture from 2.2 to 44 mW/cm2 slightly increases the quantum efficiency of DBS consumption from 4.5 to 5.9%. In this case, the selectivity of sulfoxide formation increases and the selectivity of sulfone formation decreases.

  • EFFECT OF PARAMETERS OF THE DIELECTRIC BARRIER DISCHARGE OF ATMOSPHERIC PRESSURE IN OXYGEN ON THE KINETICS OF SULFONOL DECOMPOSITION IN WATER

    E. S. Bobkova, A. A. Borzova, V. V. Rybkin, and A. I. Shishkina - 2015

    The kinetics of the decomposition of sulfonic acid and the formation of its degradation products under the action of an atmospheric pressure dielectric barrier discharge in oxygen on an aqueous solution in the power range of 0.4–4 W was measured. It is shown that the decomposition products in the liquid phase are carboxylic acids, aldehydes and carbon dioxide in the gas phase. The energy efficiency of decomposition was determined, which was (4.4–12.7) ? 10-3 molecules per 100 eV of input energy. Assumptions about the mechanisms of the ongoing processes are made.

  • Effect of the Nature of the Anion of Cationic Polymethine Dyes on the Photovoltaic Properties of Polymeric PHOTOSEMICONDUCTOR COMPOSITES

    G. V. Bulavko, N. A. Davidenko, N. A. Derevyanko, and A. A. Ishchenko - 2015

    It has been found that the nature of the anion of cationic polymethine dyes in polymer solar cells affects the photovoltage. Based on the study of spectral-luminescent properties, it was established that polymethines in them form contact ion pairs. It is shown that the difference in the behavior of anions is determined by their ability to photoinduced electron transfer in these pairs.

  • Effect of a Heavy Central Atom on the Photoelectric, Nonlinear Optical, and Photorefractive Properties of Metallophthalocyanines

    A. V. Vannikova, Yu. G. Gorbunovaa, A. D. Grishinaa, V. I. Zolotarevskiia, T. V. Krivenkob, .YU. - 2015

    Measurement of the photoelectric and photorefractive characteristics of yttrium(III) 2,3,9,10,16,17,23,24-tetra(15-crown-5)phthalocyaninatoacetate [(15C5)4Pc]Y(OAc) made it possible to reliably determine the decrease in the quantum yield of formation of charge carriers 0 and the coefficient of photorefractive two-beam amplification as the atomic weight of the central metal in the series of related gallium(III), yttrium(III), ruthenium(II), and indium(III) phthalocyaninates increases. The revealed patterns may be due to an increase in the spin-orbit interaction constant with an increase in the atomic weight of the central metal, which leads to an increase in both the contribution of triplet-excited associates to the formation of mobile charge carriers and the rate of the reverse reaction T1 S0, which effectively suppresses the formation of charge carriers through triplet excited state. The measurement of photoelectric and photorefractive characteristics at 1064 nm showed that in the polyvinylcarbazole/supramolecular ensembles of the yttrium complex, the quantum yield of electron-hole pairs is 0 = 0.6 and the two-beam gain of the laser beam is about 35 cm–1 at E0 = 120 V/μm. The dielectric susceptibility measured by the z-scan method for a solution of the yttrium complex in tetrachloroethane (1 mg in 1 ml) is (3) = 4.2 10-10 esu.

  • GAMMA RADIOLYSIS OF THE ETHANOL–WATER BINARY SYSTEM IN THE PRESENCE OF OXYGEN

    N. V. Marchenko, A. V. Nikitin, A. B. Sazonov - 2015

    Studies of gamma radiolysis of an aerated ethanol–water system in a wide range of component concentrations show that the main process occurring in such a system is the selective radiative oxidation of ethanol to acetaldehyde. By-products that accumulate in the liquid phase are 2,3-butanediol and formaldehyde. The selectivity of the process increases with an increase in the alcohol content and decreases with an increase in the irradiation dose. The theoretical model of radiolysis developed within the framework of this work gives good quantitative agreement with the experimental data. The calculated product accumulation curves have breakpoints characterized by a sharp change in the radiation-chemical yield. Their occurrence is associated with the complete burnout of oxygen in a closed system or with its insufficiently rapid entry into the liquid in a two-phase “liquid–gas” system.

  • HOLOGRAPHIC MEDIUM BASED ON A HALOGEN-CONTAINING COOLIGOMER

    P. Getmanchuk, I. I. Davidenko, N. A. Davidenko, E. V. Mokrinskaya, V. A. Pavlov, and N. G. Chuprina - 2015

    The informational properties of recording media for the photothermoplastic method of recording holograms with films of oligomeric composites based on carbazolyl-containing cooligomers, one of which contains Br atoms, have been studied. The medium based on the Br-containing co-oligomer has a higher holographic sensitivity due to the higher rate of discharge of the film surface during exposure and the formation of a latent electrostatic image.

  • STUDY OF THE INFLUENCE OF CHARGE ACCEPTERS ON THE PROCESS OF RADIATION-CHEMICAL CARBOXYLATION OF THE INDOL–SERINE SYSTEM

    L. N. Zhigunova, G. V. Nichipor, O. V. Shevtsova - 2015

    Significant interest in the radiation-chemical carboxylation of the indole-serine system is due to the prospect of its use for obtaining the essential amino acid tryptophan. In this work, we study the effect of charge acceptors, biphenyl and hydrogen peroxide, on the radiolysis kinetics of the system. It has been established that the solvated electron plays a decisive role in the mechanism of tryptophan formation.

  • PULSED HEATING OF WATER NEAR THE SURFACE OF GOLD NANOPARTICLES: FEMTOSECOND LASER SPECTROSCOPY OF ENERGY RELAXATION OF PLASMON NANOPARTICLES IN WATER COLLOID UNDER STRONG EXCITATION

    A. V. Aibush, A. A. Astaf’ev, F. E. Gostev, N. N. Denisov, V. A. Nadtochenko, A. A. Titov, A. M. Shakhov, and I. V. Shelaev - 2015

    The dynamics of differential absorption spectra of gold nanoparticles has been studied by femtosecond laser spectroscopy in a wide range of excitation energy densities. The position of the plasmon resonance peak substantially depends on the dielectric properties of the environment, which makes it possible to use plasmon nanoparticles as an optical probe. This paper demonstrates the possibility of characterizing the state of the water nanolayer surrounding the nanoparticle by femtosecond laser spectroscopy, based on the analysis of differential absorption spectra of gold nanoparticles in an aqueous colloid. In particular, at high excitation energy densities, spectral-kinetic features are revealed in the plasmon resonance absorption band, which indicate vaporization in the nanolayer around the gold particle.

Specialty code: 02.00.09 High energy chemistry

Specialty Description: High energy chemistry is a branch of chemical science that studies chemical reactions and transformations that occur in matter under the influence of nonthermal energy. The mechanisms and kinetics of such reactions and transformations are characterized by substantially nonequilibrium concentrations of fast, excited, or ionized particles with an energy greater than the energy of their thermal motion and, in some cases, chemical bonding. The carriers of non-thermal energy acting on matter are accelerated electrons and ions, fast and slow neutrons, alpha and beta particles, positrons, muons, pions, atoms and molecules at supersonic speeds, electromagnetic radiation quanta, as well as pulsed electrical, magnetic and acoustic fields. High-energy chemistry processes are distinguished by time stages into physical, occurring in femtoseconds or less, during which non-thermal energy is distributed unevenly in the medium and a "hot spot" is formed, physical-chemical, during which non-equilibrium and inhomogeneity in the "hot stain" and, finally, chemical, in which the transformations of matter obey the laws of general chemistry. The variety of types of nonthermal energy carriers causes the introduction of a number of independent areas of chemical science into the nomenclature of high energy chemistry, including laser chemistry, plasma chemistry, radiation chemistry, photochemistry, mechanochemistry, and nuclear chemistry. In research on high-energy chemistry, in addition to instrumental methods for recording fast chemical and physical processes, electronic and optical spectroscopy, mass spectrometry, resonance spectrometry, positron annihilation, methods of quantum electronics, atomic and nuclear physics, theoretical chemistry, in particular mathematical and quantum chemistry, are used. chemistry, as well as methods of physical and analytical chemistry.

Field of study:
1. Establishment of patterns of interaction of non-thermal energy carriers with matter in any state of aggregation.
2. Determination of the characteristic parameters and local distribution of non-thermal energy in the "hot spot" for various types of interaction of this energy with matter.
3. Identification, qualitative and quantitative primary products of chemical reactions in the "hot spot", their reactivity and other physical and chemical properties; study of the composition of intermediate particles and end products of chemical reactions, as well as the mechanisms and kinetics of these reactions.
4. Study of photochemical reactions, ionomolecular reactions, reactions involving solvated electrons and free radicals.
5. Determination of the resistance of compounds and materials to the effects of various carriers of non-thermal energy.
6. Application of high-energy chemistry processes in chemical synthesis, targeted modification of material properties, surface treatment and coating, industrial waste treatment and processing, and other applied chemistry problems.
7. Development, creation and optimization of technologies using high energy chemistry processes.

Branch of science:
Technical science
chemical sciences
physical and mathematical sciences

Chemistry of high energies [Electronic resource].- 2017 .- No. 2 .- 84 p. - Access mode: https://website/efd/556147

Individual articles are also available for release:
FEATURES OF THE MOLECULAR-TOPOLOGICAL STRUCTURE OF GAMMA-IRRADIATED POWDER COPOLYMER OF TETRAFLUOROETHYLENE WITH PERFLUOROVINYL PROPYL ETHER / Allayarov (200.00 rubles)
RADIATION POLYMERIZATION OF METHACRYLATES CONTROLLED BY A CHAIN ​​TRANSFER CATALYST / Roshchupkin (200.00 rubles)
GENERATION OF HYDROGEN BY HYDROREACTIVE COMPOSITIONS WITH γ-IRRADIATED ALUMINUM / Milinchuk (200.00 rubles)
RADIATION SYNTHESIS OF TETRAFLUOROETHYLENE TELOMERES IN CHLOROSILANES AND THEIR USE FOR MODIFICATION OF ALUMINOBOROSILICATE GLASS FABRIC / Kichigina (200.00 rubles)
EFFECT OF GAMMA-IRRADIATION AND THERMAL ANNEALING ON THE MOLECULAR-TOPOLOGICAL STRUCTURE OF THE COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUOROPROPYLVINYL ETHER / Olkhov (200.00 rubles)
SPECTRAL-LUMINESCENT AND QUANTUM-CHEMICAL INVESTIGATION OF ANIONIC FORMS OF 5-FLUORURACIL / Ostakhov (200.00 rubles)
EFFECT OF SUBSTITUTES ON SPECTRAL, LUMINESCENT AND SPECTRAL-KINETIC PROPERTIES OF 2,5-DIARYLIDENE DERIVATIVES OF CYCLOPENTANONE / Zakharova (200.00 rub.)
Effect of Alkanthiols on Fluorescence Twinkling of Colloidal Quantum Dots [email protected]/ Gak (200.00 rubles)
OPTIMIZATION OF THE PROCESS OF PLASMA TREATMENT OF AQUEOUS SOLUTIONS OF SODIUM CHLORIDE / Nikolenko (200.00 rubles)
CONVERSION OF HYDROCARBON GASES IN A BARRIER DISCHARGE IN THE PRESENCE OF WATER / Kudryashov (200.00 rubles)
EXPERIMENTAL STUDY OF GASIFICATION OF TARS IN A METAL MELT WITH CYCLIC SUPPLY OF CARBON-CONTAINING RAW AND OXIDANT TO THE REACTOR / Babaritsky (200.00 rubles)
MODIFICATION OF ULTRA-HIGH-MOLECULAR POLYETHYLENE IN LOW-TEMPERATURE PLASMA (REVIEW) / Gilman (200.00 rubles)
NEW DATA ON THE COMPOSITION OF PRODUCTS OF ULTRASONIC IRRADIATION OF GRAPHITE IN N-METHYLPIRROLIDONE / Shulga (200.00 rub.)
TRIPLET STATES OF BIS-CARBOCYANINE DYE AND ALBUMIN COMPLEXES / Kostyukov (200.00 rubles)

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Economics - politics - culture Theoretical and mathematical physics Theoretical basis chemical technology* Probability theory and its applications Thermal physics high temperatures* Proceedings of the V.A. Steklova* Advances in Mathematical Sciences Advances in Modern Biology Advances in Physiological Sciences Physics of the Earth* Physics and Technology of Semiconductors* Physics and chemistry glass* Physics of metals and metal science* Plasma physics* Solid state physics* Physical chemistry of surfaces and protection of materials* Plant physiology* Human physiology* functional analysis and its applications Chemical physics* Chemistry high energies* Chemistry solid fuel* Cytology* Man Ecology* Economics and mathematical methods Electrochemistry* Energy, economics, technology, ecology Ethnographic review Entomological review* Nuclear physics* * Journal materials are published by the Pleiades Publishing group in English http://www.naukaran.com The journal publishes original and review articles, short communications, letters to the editor on molecular and supramolecular photochemistry , photobiology, radiation chemistry, plasma chemistry, chemistry nanoscale systems, chemistry new atoms, processes and materials for optical information systems, on the scientific foundations of relevant technologies, as well as chronicles and reviews of books in the field chemistry high energies. magazine is 50 years old CHEMISTRY HIGH ENERGY Volume 51, Issue 2 March - April 2017 ISSN 0023-1193 ISSN 0023-1193 Chemistry high energies, 2017, Volume 51, No. 2 CONTENTS Volume 51, No. 2, 2017 RADIATION CHEMISTRY Peculiarities molecular topological buildings gamma irradiated copolymer powder tetrafluoroethylene with perfluorovinylpropyl ether S. R. Allayarov, Yu. A. Olkhov, N. N. Loginova, I. I. Sadikov, M. Yu. Tashmetov radiation polymerization methacrylates controlled by catalyst chain transfer V. P. Roshchupkin, M. P. Berezin, D. P. Kiryukhin Hydrogen generation by hydroreactive compositions<...>

Chemistry_high_energy_№2_2017.pdf

CONTENTS Volume 51, Number 2, 2017 RADIATION CHEMISTRY Peculiarities of the molecular topological structure of gamma-irradiated powdered copolymer of tetrafluoroethylene with perfluorovinyl propyl ether S. R. Allayarov, Yu. A. Olkhov, N. N. Loginova, I. I. Sadikov, M. Yu. Tashmetov Radiation polymerization of methacrylates controlled by a chain transfer catalyst V. P. Roshchupkin, M. P. Berezin, D. P. Kiryukhin Hydrogen generation by hydroreaction compositions with γ-irradiated aluminum V. K. Milinchuk, E. R. Klinshpont , V. I. Belozerov Radiation synthesis of tetrafluoroethylene telomers in chlorosilanes and their use for modifying aluminoborosilicate glass fabric G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin and perfluoropropylvinyl ether Yu. A. Olkhov, S. R. Allayarov, R. S. Allayarov, D. A. Dixon S. S. Ostakhov, M. V. Sultanbaev, M. Yu. Ovchinnikov, R. R. Kayumova, S. L. Khursan Effect of substituents on the spectral, luminescent and spectral-kinetic properties of 2,5-diarylidene derivatives of cyclopentanone G. V. Zakharova, F. S. Zyuzkevich, V. N. Gutrov, G. V. Gavrilova, V. N. Nuriev, S. Z. Vatsadze, V. G. Plotnikov, S. P. Gromov, A. K. Chibisov Effect of Alkanthiols on Fluorescence Flickering of Colloidal Quantum Dots [email protected] V. Yu. Gak, S. A. Tovstun, M. G. Spirin, S. B. Brichkin, V. F. Razumov PLASMA CHEMISTRY Optimization of the process of plasma treatment of aqueous solutions of sodium chloride N. V. Nikolenko, R. I. Zakharov, A. V. Dubenko, G. V. Moleva, T. N. Avdienko Conversion of hydrocarbon gases in a barrier discharge in the presence of water S. V. Kudryashov, A. Yu. Ryabov, A. N. Ocheredko Experimental study of tar gasification in metal melt with cyclic supply of carbon-containing raw materials and oxidant to the reactor A. I. Babaritsky, M. B. Bibikov, M. A. Deminsky, S. A. Demkin, S. V. Korobtsev, M. F. Krotov, B. V. Potapkin , R. V. Smirnov, F. N. Chebankov Modification of ultra-high molecular weight polyethylene in low-temperature plasma (Review) A. B. Gilman, M. S. Piskarev, A. A. Kuznetsov, A. N. Ozerin 147 142 131 137 121 126 116 109 103 99 94 85

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SONOCHEMISTRY New data on the composition of graphite ultrasonic irradiation products in N-methylpyrrolidone Yu. M. Shulga, AS Lobach, FO Milovich, N. Yu. Shulga, DA Kiselev, SA Baskakov PHOTOCHEMISTRY Triplet states of complexes of bis-carbocyanine dye and albumin A. A. Kostyukov, T. D. Nekipelova, A. Sh. Pablo J. Gonçalves, André L. S. Pavanelli, Lucimara P. Ferreira, Andre M. Amado, Yu. E. Borisevich, and V. A. Kuzmin Conv. oven l. 10.25 arb. kr.-ott. 0.6 thousand. Circulation 52 copies. Law 84 Publication date 03/23/2017 Format 60 H 881/8 Uch.-ed. l. 10.25 Boom. l. 5.1 Free price Founders: Russian Academy of Sciences, Center for Photochemistry RAS Publisher: Russian Academy of Sciences. Nauka Publishing House, 117997, Moscow, Profsoyuznaya st., 90